{"id":1969,"date":"2023-10-26T06:16:49","date_gmt":"2023-10-26T06:16:49","guid":{"rendered":"https:\/\/www.nanosciences-spm-uhv.com\/?p=1969"},"modified":"2023-10-26T06:20:43","modified_gmt":"2023-10-26T06:20:43","slug":"pub14","status":"publish","type":"post","link":"https:\/\/www.nanosciences-spm-uhv.com\/en\/pub14\/","title":{"rendered":"Highly Conductive Tungsten Suboxide Nanotubes."},"content":{"rendered":"<p>We demonstrate a high electron conductivity (&gt;100 S\/cm and up to 1000 S\/cm) of tungsten suboxide W(18)O(52.4-52.9) (or equivalently WO(2.91-2.94)) nanotubes (2-3 nm in diameter, \u223c \u00b5m long). The conductivity is measured in the temperature range 120 to 300K by a four-probe scanning tunneling microscope in ultra-high vacuum. The nanotubes are synthesized by a low-temperature and low-cost solvothermal method. They self-assemble in bundles of hundreds of nanotubes forming nanowires (\u223c \u00b5m long, few tens nm wide). We observe a large anisotropy of the conductivity with a ratio (longitudinal conductivity\/perpendicular conductivity) of \u223c 1E5. A large fraction of them (\u223c 65-95%) shows a metallic-like, thermal activation less, electron transport behavior. Few of them, with a lower conductivity from 10 to 100 S\/cm, display a variable range hopping behavior. In this latter case, a hopping barrier energy of \u223c 0.24 eV is inferred in agreement with the calculated energy level of the oxygen vacancy below the conduction band. This result is in agreement with a relative average concentration of oxygen vacancies of \u223c 3%, for which a semiconductor-to-metal transition was theoretically predicted. These tungsten suboxide nanostructures are prone to a wide range of applications in nanoelectronics.<\/p>\n\n\n<div style=\"height:14px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n\n\n\n<div class=\"wp-block-uagb-buttons uagb-buttons__outer-wrap uagb-btn__medium-btn uagb-btn-tablet__default-btn uagb-btn-mobile__default-btn uagb-block-d061a050\"><div class=\"uagb-buttons__wrap uagb-buttons-layout-wrap\">\n<div class=\"wp-block-uagb-buttons-child uagb-buttons__outer-wrap uagb-block-f2c18d19 wp-block-button\"><div class=\"uagb-button__wrapper\"><a class=\"uagb-buttons-repeater wp-block-button__link\" href=\"https:\/\/www.nanosciences-spm-uhv.com\/en\/pub14\/10.1063\/5.0170761\/\" onclick=\"return true;\" rel=\"nofollow noopener\" target=\"_blank\"><div class=\"uagb-button__link\">Full text<\/div><span class=\"uagb-button__icon uagb-button__icon-position-after\"><svg xmlns=\"https:\/\/www.w3.org\/2000\/svg\" viewbox=\"0 0 448 512\"><path d=\"M438.6 278.6l-160 160C272.4 444.9 264.2 448 256 448s-16.38-3.125-22.62-9.375c-12.5-12.5-12.5-32.75 0-45.25L338.8 288H32C14.33 288 .0016 273.7 .0016 256S14.33 224 32 224h306.8l-105.4-105.4c-12.5-12.5-12.5-32.75 0-45.25s32.75-12.5 45.25 0l160 160C451.1 245.9 451.1 266.1 438.6 278.6z\"><\/path><\/svg><\/span><\/a><\/div><\/div>\n\n\n\n<div class=\"wp-block-uagb-buttons-child uagb-buttons__outer-wrap uagb-block-96a04489 wp-block-button\"><div class=\"uagb-button__wrapper\"><a class=\"uagb-buttons-repeater wp-block-button__link\" href=\"https:\/\/www.nanosciences-spm-uhv.com\/en\/gdr\/publications\/\" onclick=\"return true;\" rel=\"follow noopener\" target=\"_self\"><div class=\"uagb-button__link\">Back to publication<\/div><span class=\"uagb-button__icon uagb-button__icon-position-after\"><svg xmlns=\"https:\/\/www.w3.org\/2000\/svg\" viewbox=\"0 0 448 512\"><path d=\"M438.6 278.6l-160 160C272.4 444.9 264.2 448 256 448s-16.38-3.125-22.62-9.375c-12.5-12.5-12.5-32.75 0-45.25L338.8 288H32C14.33 288 .0016 273.7 .0016 256S14.33 224 32 224h306.8l-105.4-105.4c-12.5-12.5-12.5-32.75 0-45.25s32.75-12.5 45.25 0l160 160C451.1 245.9 451.1 266.1 438.6 278.6z\"><\/path><\/svg><\/span><\/a><\/div><\/div>\n<\/div><\/div>\n\n\n\n<div style=\"height:14px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n<p>DOI : <a href=\"https:\/\/doi.org\/10.1063\/5.0170761\">10.1063\/5.0170761<\/a><\/p><p>Authors : C\u00e9cile Huez, Maxime Berthe, Florence Volatron, Jean-Michel Guigner, Dalil Brouri, Lise-Marie Chamoreau, Beno\u00eet Baptiste, Anna Proust, Dominique Vuillaume.<\/p>","protected":false},"excerpt":{"rendered":"<p>We demonstrate a high electron conductivity (&gt;100 S\/cm and up to 1000 S\/cm) of tungsten suboxide W(18)O(52.4-52.9) (or equivalently WO(2.91-2.94)) nanotubes (2-3 nm in diameter, \u223c \u00b5m long). The conductivity is measured in the temperature range 120 to 300K by a four-probe scanning tunneling microscope in ultra-high vacuum. The nanotubes are synthesized by a low-temperature<\/p><\/div>\n<div class=\"blog-btn\"><a href=\"https:\/\/www.nanosciences-spm-uhv.com\/en\/pub14\/\" class=\"home-blog-btn\">Read More<\/a><\/p>","protected":false},"author":1,"featured_media":1971,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_uag_custom_page_level_css":"","footnotes":""},"categories":[22],"tags":[27],"class_list":["post-1969","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-axe4","tag-axe4"],"uagb_featured_image_src":{"full":["https:\/\/www.nanosciences-spm-uhv.com\/wp-content\/uploads\/2023\/10\/Capture-decran-2023-10-11-a-9.03.34-PM.png",567,267,false],"thumbnail":["https:\/\/www.nanosciences-spm-uhv.com\/wp-content\/uploads\/2023\/10\/Capture-decran-2023-10-11-a-9.03.34-PM-150x150.png",150,150,true],"medium":["https:\/\/www.nanosciences-spm-uhv.com\/wp-content\/uploads\/2023\/10\/Capture-decran-2023-10-11-a-9.03.34-PM-300x141.png",300,141,true],"medium_large":["https:\/\/www.nanosciences-spm-uhv.com\/wp-content\/uploads\/2023\/10\/Capture-decran-2023-10-11-a-9.03.34-PM.png",567,267,false],"large":["https:\/\/www.nanosciences-spm-uhv.com\/wp-content\/uploads\/2023\/10\/Capture-decran-2023-10-11-a-9.03.34-PM.png",567,267,false],"1536x1536":["https:\/\/www.nanosciences-spm-uhv.com\/wp-content\/uploads\/2023\/10\/Capture-decran-2023-10-11-a-9.03.34-PM.png",567,267,false],"2048x2048":["https:\/\/www.nanosciences-spm-uhv.com\/wp-content\/uploads\/2023\/10\/Capture-decran-2023-10-11-a-9.03.34-PM.png",567,267,false],"trp-custom-language-flag":["https:\/\/www.nanosciences-spm-uhv.com\/wp-content\/uploads\/2023\/10\/Capture-decran-2023-10-11-a-9.03.34-PM-18x8.png",18,8,true],"sow-carousel-default":["https:\/\/www.nanosciences-spm-uhv.com\/wp-content\/uploads\/2023\/10\/Capture-decran-2023-10-11-a-9.03.34-PM-272x182.png",272,182,true]},"uagb_author_info":{"display_name":false,"author_link":"https:\/\/www.nanosciences-spm-uhv.com\/en\/author\/zpqq18wlui98\/"},"uagb_comment_info":0,"uagb_excerpt":"We demonstrate a high electron conductivity (&gt;100 S\/cm and up to 1000 S\/cm) of tungsten suboxide W(18)O(52.4-52.9) (or equivalently WO(2.91-2.94)) nanotubes (2-3 nm in diameter, \u223c \u00b5m long). The conductivity is measured in the temperature range 120 to 300K by a four-probe scanning tunneling microscope in ultra-high vacuum. The nanotubes are synthesized by a low-temperatureRead&hellip;","_links":{"self":[{"href":"https:\/\/www.nanosciences-spm-uhv.com\/en\/wp-json\/wp\/v2\/posts\/1969","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.nanosciences-spm-uhv.com\/en\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.nanosciences-spm-uhv.com\/en\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.nanosciences-spm-uhv.com\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.nanosciences-spm-uhv.com\/en\/wp-json\/wp\/v2\/comments?post=1969"}],"version-history":[{"count":5,"href":"https:\/\/www.nanosciences-spm-uhv.com\/en\/wp-json\/wp\/v2\/posts\/1969\/revisions"}],"predecessor-version":[{"id":2052,"href":"https:\/\/www.nanosciences-spm-uhv.com\/en\/wp-json\/wp\/v2\/posts\/1969\/revisions\/2052"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.nanosciences-spm-uhv.com\/en\/wp-json\/wp\/v2\/media\/1971"}],"wp:attachment":[{"href":"https:\/\/www.nanosciences-spm-uhv.com\/en\/wp-json\/wp\/v2\/media?parent=1969"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.nanosciences-spm-uhv.com\/en\/wp-json\/wp\/v2\/categories?post=1969"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.nanosciences-spm-uhv.com\/en\/wp-json\/wp\/v2\/tags?post=1969"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}